Welcome to ChE 503, an advanced thermodynamics course primarily for chemical
engineering graduate students.
The course assumes that you had one prior course in classical thermodynamics.
Time and place
There are usually two lectures and a precept per week, on Mondays 11 - 12:20 at Friend Center 111 and on Tuesdays and Thursdays at 1:30 - 2:50 in A224 E-Quad (Elgin Seminar Room). At the precept, we go over lecture material in more detail or go over problems.
Books
The recommended textbook is J. W. Tester and M. Modell, "Thermodynamics and its Applications," 3d ed., Prentice-Hall (1996). Chapter numbers and homework problems in the course schedule shown on the syllabus pages refer to this book. See http://web.mit.edu/testerel/thermo/ for current errata list and answers to selected problems.
Other useful reference books (no need to buy these):
J.M. Prausnitz et al., "Molecular Thermodynamics of Fluid-Phase
Equilibria", 2d ed., Prentice-Hall (1986).
D. Chandler, "Introduction to Modern Statistical Mechanics" Oxford
University Press (1987).
H.B. Callen, "Thermodynamics and an Introduction to
Thermostatistics," 2d ed., Wiley (1985).
Problem sets
Please bring the completed problem sets as indicated on the schedule. A personal computer may be helpful for arriving to a final numerical solution in some problems.
Grading
The grade for the course will be based on the midterm and final exams (70%) problem sets (25%) and class participation (5%).
Staff
Instructor: Thanos Panagiotopoulos, A-317 E-Quad., x8-4591 (azp@princeton.edu).
Office hours: Wed. & Fri. 3-4.
AI: Jonathan Davis, G-109, x8-0206 (jrdavis@princeton.edu).
Office hours: TBA.
Web Site
Lecture notes, revised class schedule, problem set solutions and other course-related material will be continuously available from the course web site, http://kea.princeton.edu/ChE503/index.html. A backup server is also available: http://tilos.princeton.edu/ChE503/index.html.
Tentative Class Syllabus: 01/18/2007
Lec.# | Date | Topic(s) |
Chapter | Problem Set Due | |
1 | Th | 9/14 | Introduction, Basic Concepts and Definitions | 1,2 | |
2 | Mo | 9/18 | Energy and First Law | 3 | |
Tu | 9/19 | Precept # 1 | |||
3 | Th | 9/21 | Reversibility | 4 | PS1: 3.1, 3.9 |
4 | Mo | 9/25 | Fundamental Equation and Second Law | 4 | |
Tu | 9/26 | Precept # 2 | |||
5 | Th | 9/28 | Legendre transformations | 5 | PS2: 4.5, 4.8, 4.17 |
6 | Mo | 10/2 | Legendre transformations (cont.) | 5 | |
Tu | 10/3 | Precept # 3 | |||
7 | Th | 10/5 | Equilibrium | 6 | PS3: 5.3, 5.9, 5.30 |
8 | Mo | 10/9 | Stability | 7 | |
Tu | 10/10 | Precept # 4 | |||
9 | Th | 10/12 | Mixture Properties | 9 | PS4: 6.6, 6.7,7.5,7.8 |
10 | Mo | 10/16 | Fugacities and Activities | 9 | |
Tu | 10/17 | Precept # 5 | |||
Th | 10/19 | Thermodynamics for the Hydrogen Economy (Dr. Vern Weekman) | PS5: 9.1, 9.9, 9.13 | ||
Mo | 10/23 | MidTerm Exam: covers chapters 1-7, 9 | |||
11 | Tu | 10/24 | Statistical Mechanical Ensembles | Notes, 10 | |
12 | Th | 10/26 | Statistical Mechanical Ensembles (cont) | Notes, 10 | |
Mo | 11/6 | Precept # 6 | |||
13 | Tu | 11/7 | Boltzmann Statistics and Ideal Monoatomic gases | Notes, 10 | PS6 |
14 | Th | 11/9 | Virial Expansions | Notes, 10 | |
Mo | 11/13 | No Precept (AIChE mtg) | |||
Tu | 11/14 | No Class (AIChE mtg) | |||
Th | 11/16 | Precept # 7 | |||
15 | Mo | 11/27 | Distribution Functions; movie, g(r) | Notes, 10 | PS7 |
Tu | 11/28 | No precept | |||
16 | Th | 11/30 | Monte Carlo methods | ||
17 | Mo | 12/4 | Monte Carlo methods (cont.) | ||
Tu | 12/5 | Precept #8 | |||
18 | Th | 12/7 | A virtual MC example, intro to MD | Notes | PS8 |
19 | Mo | 12/11 | Phase Transitions | Notes | |
Tu | 12/12 | Precept # 9 | |||
20 | Th | 12/14 | Monte Carlo for phase transitions | Notes, 11 | PS9 |
21 | Tu | 1/9 | Phase Equilibrium | 15 | |
22 | Th | 1/11 | Chemical Equilibrium | 16 | |
Tu | 1/16 | Review session | PS10: 15.12, 16.3, 16.12 | ||
TBA | Final Exam |