Welcome to ChE 503, an advanced thermodynamics course primarily for chemical engineering graduate students.
The course assumes that you had one prior course in classical thermodynamics.
 

Time and place

There are usually two lectures and a precept per week, on Mondays 11 - 12:20 at Friend Center 111 and on Tuesdays and Thursdays at 1:30 - 2:50 in A224 E-Quad (Elgin Seminar Room).   At the precept, we go over lecture material in more detail or go over problems.  

Books

The recommended textbook is J. W. Tester and M. Modell, "Thermodynamics and its Applications," 3d ed., Prentice-Hall (1996). Chapter numbers and homework problems in the course schedule shown on the syllabus pages refer to this book.  See  http://web.mit.edu/testerel/thermo/ for current errata list and answers to selected problems.

Other useful reference books (no need to buy these):

J.M. Prausnitz et al., "Molecular Thermodynamics of Fluid-Phase Equilibria", 2d ed., Prentice-Hall (1986).
D. Chandler, "Introduction to Modern Statistical Mechanics" Oxford University Press (1987).
H.B. Callen, "Thermodynamics and an Introduction to Thermostatistics," 2d ed., Wiley (1985).

Problem sets

Please bring the completed problem sets as indicated on the schedule. A personal computer may be helpful for arriving to a final numerical solution in some problems.

Grading

The grade for the course will be based on the midterm and final exams (70%) problem sets (25%) and class participation (5%).

Staff

Instructor: Thanos Panagiotopoulos, A-317 E-Quad., x8-4591 (azp@princeton.edu). Office hours: Wed. & Fri. 3-4.
AI: Jonathan Davis, G-109, x8-0206 (jrdavis@princeton.edu). Office hours: TBA.

Web Site

Lecture notes, revised class schedule, problem set solutions and other course-related material will be continuously available from the course web site, http://kea.princeton.edu/ChE503/index.html.  A backup server is also available: http://tilos.princeton.edu/ChE503/index.html.

 

Tentative Class Syllabus: 01/18/2007

Lec.# Date

Topic(s)

Chapter Problem Set Due
1 Th 9/14 Introduction, Basic Concepts and Definitions 1,2  
2 Mo 9/18 Energy and First Law 3
Tu 9/19 Precept # 1  
3 Th 9/21 Reversibility 4 PS1: 3.1, 3.9
4 Mo 9/25 Fundamental Equation and Second Law 4
Tu 9/26 Precept # 2  
5 Th 9/28 Legendre transformations 5 PS2: 4.5, 4.8, 4.17
6 Mo 10/2 Legendre transformations (cont.) 5
Tu 10/3 Precept # 3  
7 Th 10/5 Equilibrium 6 PS3: 5.3, 5.9, 5.30
8 Mo 10/9 Stability 7
Tu 10/10 Precept # 4  
9 Th 10/12 Mixture Properties  9 PS4: 6.6, 6.7,7.5,7.8
10 Mo 10/16 Fugacities and Activities 9
Tu 10/17 Precept # 5  
Th 10/19 Thermodynamics for the Hydrogen Economy (Dr. Vern Weekman) PS5: 9.1, 9.9, 9.13
Mo 10/23 MidTerm Exam: covers chapters 1-7, 9
11 Tu 10/24 Statistical Mechanical Ensembles Notes, 10  
12 Th 10/26 Statistical Mechanical Ensembles (cont) Notes, 10
Mo 11/6 Precept # 6
13 Tu 11/7 Boltzmann Statistics and Ideal Monoatomic gases Notes, 10  PS6
14 Th 11/9 Virial Expansions Notes, 10  
Mo 11/13 No Precept (AIChE mtg)
Tu 11/14 No Class (AIChE mtg)  
Th 11/16 Precept # 7
15 Mo 11/27 Distribution Functions; movie, g(r) Notes, 10 PS7
Tu 11/28 No precept
16 Th 11/30 Monte Carlo methods  
17 Mo 12/4 Monte Carlo methods (cont.)
Tu 12/5 Precept #8  
18 Th 12/7 A virtual MC example, intro to MD  Notes PS8
19 Mo 12/11 Phase Transitions Notes
Tu 12/12 Precept # 9  
20 Th 12/14 Monte Carlo for phase transitions Notes, 11 PS9
21 Tu 1/9 Phase Equilibrium 15
22 Th 1/11 Chemical Equilibrium 16  
Tu 1/16 Review session PS10: 15.12,  16.3, 16.12
  TBA Final Exam